侵蚀-沉积对土壤重金属形态、浓度及富集影响的研究进展
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贵州大学

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中图分类号:

X53

基金项目:

国家自然科学基金项目“喀斯特地质高背景区坡耕地土壤侵蚀对Cd迁移的作用机制”(42367047);自然资源部岩溶生态系统与石漠化治理重点实验室开放基金专项/广西岩溶动力学重大科技创新基地开放课题“喀斯特区浅层岩溶裂隙土壤漏失对Cd迁移的影响机制”(YRSW-2023-086);中国科学院水利部水土保持研究所黄土高原土壤侵蚀与旱地农业国家重点实验室基金“地球化学异常区坡耕地地表/地下土壤侵蚀对镉迁移的影响规律”(F2010121002-202416)


Research progress on the effects of erosion and sedimentation on the form, concentration and enrichment of heavy metal(loid)s in soil
Author:
Affiliation:

Guizhou University

Fund Project:

The National Natural Science Foundation of China (NSFC), "Mechanism of soil erosion on Cd migration in sloping farmland in Karst high background Area" (42367047); Key Laboratory of Karst Ecosystem and Rocky Desertification Control, Ministry of Natural Resources/Project of Karst Dynamics Major Science and Technology Innovation Base of Guangxi "Mechanism of influence of soil leakage in shallow karst Fractures on Cd migration in Karst Area" (YRSW-2023-086); State Key Laboratory of Soil Erosion and Dryland Agriculture in the Loess Plateau, Institute of Soil and Water Conservation, Ministry of Water Resources, Chinese Academy of Sciences, Foundation of Surface/Subsurface Soil Erosion on Cadmium Migration in Sloping Farmland in Geochemical Anomaly Area, F2010121002-202416

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    摘要:

    [目的]探讨侵蚀-沉积对土壤重金属形态、浓度和富集特征的作用规律,旨在深入认识侵蚀-沉积对土壤重金属形态、浓度和富集的影响机制,为流域土壤重金属污染防治提供科学依据。[方法]基于国内外有关侵蚀-沉积对土壤重金属影响的相关文章,对侵蚀-沉积过程中影响土壤重金属的关键因素进行系统分析研究。[结果](1)侵蚀作用通过径流冲刷导致土壤重金属含量在空间分布上产生差异,降雨促使重金属由颗粒态向可溶解态转化,沉积作用下重金属的形态可能发生转化,沉积环境中土壤团聚体和粘土含量影响重金属分布和富集;(2)有机质对重金属具有双重作用,既能吸附游离态重金属离子,降低土壤中重金属的交换态含量,又能与重金属发生络合作用,提高重金属的有机结合态含量;(3)土壤氢离子浓度指数(pH) 和阳离子交换量(CEC)对重金属形态的转化具有显著影响,酸性条件下促进重金属离子间络合、沉淀等作用,而碱性条件下土壤颗粒表面正电荷增加与土壤重金属离子所带正电荷相排斥,进而影响土壤颗粒表面与重金属离子之间吸附;(4)一般土壤水分越高重金属的溶解度越大,但过量的水分会导致氧气不足,降低氧化还原电位,从而影响重金属的还原释放,氧化还原电位(Eh)的变化直接影响到土壤中铁锰氧化物和硫化物的稳定性,进而影响重金属的浓度变化。[结论]侵蚀-沉积过程中土壤重金属形态、浓度和富集特征受多种环境因子共同作用,呈现侵蚀区到沉积区显著的差异,未来研究应进一步加强小流域尺度的长期野外监测,明确在侵蚀-沉积下土壤理化性质对重金属形态、浓度及富集的共同作用,并建立更为精确的土壤重金属迁移模型。

    Abstract:

    [Objective] To investigate the effect of erosion and sedimentation on the form, concentration and enrichment characteristics of heavy metals in soil, so as to further understand the mechanism of the influence of erosion and sedimentation on the form, concentration and enrichment of heavy metals in soil, and provide scientific reference for the prevention and control of soil heavy metal pollution in river basins. [Methods] Based on the relevant articles about the influence of erosion-deposition on heavy metals in soil, the key factors affecting heavy metals in soil during erosion-deposition were systematically studied. [Results] (1) Erosion causes differences in the spatial distribution of heavy metal content in soil through runoff erosion, rainfall promotes the transformation of the form of heavy metal from granular to soluble, and the form of heavy metal may be transformed under sedimentation. Soil aggregates and clay contents in sedimentary environment affect the distribution and enrichment of heavy metals. (2) Organic matter has dual effects on heavy metals, which can adsorb free heavy metal ions, reduce the exchange state content of heavy metals in soil, and can also be complexed with heavy metals to increase the organic binding state content of heavy metals. (3) Soil hydrogenionconcentration (pH) and cationexchangecapacity (CEC) have significant effects on the transformation of heavy metal forms. Under acidic conditions, the complexation and precipitation between heavy metal ions are promoted, while under alkaline conditions, the positive charge on the surface of soil particles increases and repelling the positive charge carried by soil heavy metal ions, thus affecting the adsorption between the surface of soil particles and heavy metal ions. (4) Generally, the higher the soil moisture, the greater the solubility of heavy metals, but excessive water will lead to insufficient oxygen and reduce the redox potential, thus affecting the reduction release of heavy metals. Changes in the redox potential (Eh) directly affect the stability of iron and manganese oxides and sulfides in the soil, and then affect the concentration change of heavy metals. [Conclusion] The form, concentration and enrichment characteristics of heavy metals in soil during erosion-deposition process are affected by various environmental factors, showing significant differences from the erosion area to the deposition area. Future studies should further explore the mechanism and mechanism of soil heavy metal form transformation under different environmental conditions, and clarify the specific influence of soil aggregate and texture on the enrichment characteristics of heavy metals. A more accurate model of heavy metal migration in soil was established.

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  • 收稿日期:2024-07-03
  • 最后修改日期:2024-08-27
  • 录用日期:2024-08-27
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